Real-Time Monitoring of Strain Accumulation and Relief during Epitaxy of Ultrathin Co Ferrite Films with Varied Co Content
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https://doi.org/10.48693/516
https://doi.org/10.48693/516
Full metadata record
DC Field | Value | Language |
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dc.creator | Thien, Jannis | - |
dc.creator | Rodewald, Jari | - |
dc.creator | Pohlmann, Tobias | - |
dc.creator | Ruwisch, Kevin | - |
dc.creator | Bertram, Florian | - |
dc.creator | Küpper, Karsten | - |
dc.creator | Wollschläger, Joachim | - |
dc.date.accessioned | 2024-02-28T09:35:08Z | - |
dc.date.available | 2024-02-28T09:35:08Z | - |
dc.date.issued | 2023-11-23 | - |
dc.identifier.citation | Thien J, Rodewald J, Pohlmann T, Ruwisch K, Bertram F, Küpper K, Wollschläger J.: Real-Time Monitoring of Strain Accumulation and Relief during Epitaxy of Ultrathin Co Ferrite Films with Varied Co Content. Materials. 2023; 16(23):7287 | ger |
dc.identifier.uri | https://doi.org/10.48693/516 | - |
dc.identifier.uri | https://osnadocs.ub.uni-osnabrueck.de/handle/ds-2024022810912 | - |
dc.description.abstract | Ultrathin Co𝑥Fe3−𝑥O4 films of high structural quality and with different Co content (x = 0.6–1.2) were prepared by reactive molecular beam epitaxy on MgO(001) substrates. Epitaxy of these ferrite films is extensively monitored by means of time-resolved (operando) X-ray diffraction recorded in out-of-plane geometry to characterize the temporal evolution of the film structure. The Co ferrite films show high crystalline ordering and smooth film interfaces independent of their Co content. All Co𝑥Fe3−𝑥O4 films exhibit enhanced compressive out-of-plane strain during the early stages of growth, which partly releases with increasing film thickness. When the Co content of the ferrite films increases, the vertical-layer distances increase, accompanied by slightly increasing film roughnesses. The latter result is supported by surface-sensitive low-energy electron diffraction as well as X-ray reflectivity measurements on the final films. In contrast, the substrate–film interface roughness decreases with increasing Co content, which is confirmed with X-ray reflectivity measurements. In addition, the composition and electronic structure of the ferrite films is characterized by means of hard X-ray photoelectron spectroscopy performed after film growth. The experiments reveal the expected increasing Fe3+/Fe2+ cation ratios for a higher Co content. | eng |
dc.relation | https://doi.org/10.3390/ma16237287 | ger |
dc.rights | Attribution 4.0 International | * |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | * |
dc.subject | cobalt ferrite | eng |
dc.subject | ultrathin films | eng |
dc.subject | strain | eng |
dc.subject | X-ray diffraction | eng |
dc.subject.ddc | 530 - Physik | ger |
dc.title | Real-Time Monitoring of Strain Accumulation and Relief during Epitaxy of Ultrathin Co Ferrite Films with Varied Co Content | eng |
dc.type | Einzelbeitrag in einer wissenschaftlichen Zeitschrift [Article] | ger |
orcid.creator | https://orcid.org/0000-0001-5551-7240 | - |
orcid.creator | https://orcid.org/0000-0002-3043-3718 | - |
orcid.creator | https://orcid.org/0000-0003-0364-9385 | - |
orcid.creator | https://orcid.org/0000-0001-9304-3015 | - |
dc.identifier.doi | 10.3390/ma16237287 | - |
Appears in Collections: | FB06 - Hochschulschriften Open-Access-Publikationsfonds |
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File | Description | Size | Format | |
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Thien_etal_materials-16-07287_2023.pdf | Article | 792,46 kB | Adobe PDF | Thien_etal_materials-16-07287_2023.pdf View/Open |
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